TRIMETHYLSILYLFLUOROSULFONATE (TMSOFS) - AN ALTERNATIVE TO TMS TRIFLATE AS A SOURCE OF ME3SI+

被引：24

作者：

LIPSHUTZ, BH ^{[1
]}

BURGESSHENRY, J ^{[1
]}

ROTH, GP ^{[1
]}

机构：

[1] BRISTOL MYERS SQUIBB,WALLINGFORD,CT 06492

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 06期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)77474-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Generation of trimethylsilylfluorosulfonate in situ provides a useful source of TMS+, the reactivity of which is essentially equivalent to that of TMS triflate. Its precursors, in particular FSO3H, are less costly than those of TMSOTf or the reagent itself

引用

页码：995 / 998

页数：4

共 19 条

[1] SUPER-ACID CATALYZED ADDITION OF ALLYLSILANES TO CARBONYL-COMPOUNDS - SYNTHETIC AND MECHANISTIC ASPECTS [J].