AN NMR STUDY OF URANYL 2-THENOYLTRIFLUOROACETYLACETONATE COMPLEXES WITH LIGANDS

被引：16

作者：

SIDDALL, TH

STEWART, WE

机构：

[1] Savannah River Laboratory, E. I. du Pont de Nemours and Company, Aiken

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 11期

关键词：

D O I：

10.1016/0022-1902(69)80343-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1H, 19F, and 31P magnetic resonance spectroscopy of the complex molecules UO2(TTA)2·L TTA = 2-thenoyltrifluoromethylacetylacetone and L = tri-n-butyl phosphate, trioctyl phosphine oxide, or dimethyl formamide) show that L is directly bonded to uranium. A pentagonal bipyramidal structure is proposed for these complexes with two out of three possible cis-trans isomers being found. © 1969.

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页码：3557 / &

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