A NOVEL SYNTHESIS OF NEOPENTYLBENZENES

被引：10

作者：

BASSINDALE, AR

EABORN, C

WALTON, DRM

机构：

[1] School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ, Sussex

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 18期

关键词：

D O I：

10.1039/j39690002505

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzyl chlorides react with t-butyl-lithium in a mixture of pentane and hexane to give neopentylbenzenes, XC6H4·CH2But. Yields were (X =) H, 75; o-Me, 25: m-Me, 55; p-Me, 62; m-F, 70; p-F, 70; m-Cl, 60; p-Cl, 69; p-Br, 60%.

引用

页码：2505 / +

页数：1

共 11 条

[1] HYPERCONJUGATION .3. RELATIVE RATES OF BROMINATION OF 12 MONOALKYLBENZENES [J].

BERLINER, E ;

BERLINER, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (04) :1195-1200

[2] REDUCTIONS AT METAL SURFACES .3. CLEMMENSEN REDUCTION OF SOME STERICALLY-HINDERED KETONES [J].

BREWSTER, JH ;

PATTERSON, J ;

FIDLER, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (24) :6368-6371

[3] On 1-phenyl-2 2-dimethyl-propane, a new ayml benzene [J].

Bygden, A .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1912, 45 :3479-3483

[4]

EMSLEY JW, 1966, HIGH RESOLUTION NUCL, V2, P1123

[5] THE SYNTHESIS OF SOME ALKOXY-SUBSTITUTED AND ALKYL-SUBSTITUTED TETRAPHENYLCYCLOPENTADIENONES [J].

FRIEDMAN, A ;

GUGIG, W ;

MEHR, L ;

BECKER, EI .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (04) :516-520

[6] THE ANALYSIS OF ORGANIC-SUBSTITUTED GROUP-IVB LITHIUM COMPOUNDS [J].

GILMAN, H ;

CARTLEDGE, FK ;

SIM, SY .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1963, 1 (01) :8-14

[7] ISOMER DISTRIBUTIONS IN ELECTROPHILIC SUBSTITUTION REACTIONS OF NEOPENTYLBENZENE [J].

GURKA, DF ;

SCHUBERT, WM .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (10) :3416-&

[8] IONIZATION AND DISSOCIATION EQUILIBRIA IN LIQUID SULFUR DIOXIDE .9. M- AND RHO-NEOPENTYL DERIVATIVES OF TRIPHENYLCHLOROMETHANE AT 0.00 DEGREES [J].

LICHTIN, NN ;

ROWE, PE ;

PUAR, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (22) :4259-&

[9] ALUMINIUMCHLORID-KATALYSEN .25. EINE NEUE UMLAGERUNG DER PHENYLALKANE [J].

NENITZESCU, CD ;

NECSOIU, I ;

GLATZ, A ;

ZALMAN, M .

CHEMISCHE BERICHTE-RECUEIL, 1959, 92 (01) :10-17

[10] A NEW METHOD IN INTRODUCING NEOPENTYL GROUP [J].

NEWMAN, MS ;

GILL, N .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (11) :3860-&

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