RADICAL ISOMERIZATION VIA INTRAMOLECULAR IPSO SUBSTITUTION OF N-ARYLAMIDES - ARYL TRANSLOCATION FROM NITROGEN TO CARBON

被引：26

作者：

LEE, E

WHANG, HS

CHUNG, CK

机构：

[1] Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 06期

关键词：

D O I：

10.1016/0040-4039(94)02370-Q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Aryl-N-(3-bromopropyl)amides are converted to N-(3-arylpropyl)amides under standard radical generating conditions via intramolecular ipso attack of the alkyl radicals which generates spiro cyclohexadienyl radical intermediates.

引用

页码：913 / 914

页数：2

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[2] ELECTROCHEMICAL REACTIONS .24. REDUCTIVE CYCLIZATION OF I-(2-HALOGENOPHENYL)-J-PHENYL COMPOUNDS - A GENERAL REACTION
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[3] ELECTROCHEMICAL REACTIONS .23. INTRAMOLECULAR RADICAL SUBSTITUTION DURING THE REDUCTION OF 2-HALOGENO-N-METHYL-N-NAPHTHYL-BENZAMIDES
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[4] AROMATIC ANNELATION BY REACTION OF ARYLIMIDOYL RADICALS WITH ALKYNES - EVIDENCE FOR THE INTERVENTION OF A SPIROCYCLOHEXADIENYL RADICAL IN THE SYNTHESIS OF SUBSTITUTED QUINOLINES
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[5] LEE E, 1993, TETRAHEDRON LETT, V34, P2343

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