NICKEL-CATALYZED AMINATION OF BUTADIENE

被引：19

作者：

AKERMARK, B ^{[1
]}

AKERMARK, G ^{[1
]}

MOBERG, C ^{[1
]}

BJORKLUND, C ^{[1
]}

SIIRALAHANSEN, K ^{[1
]}

机构：

[1] SPECIALTY CHEM DIV KEMANOBEL,S-10061 STOCKHOLM,SWEDEN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)83125-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dialkyloctadienylamines are formed selectively and in high yields upon reaction of secondary amines with butadiene in the presence of catalytic amounts of nickel(II) acetylacetonate, triphenylphosphine and triethylaluminium. Similar results are obtained by using a catalyst prepared by addingg a Lewis acid, e.g. triethylaluminium or boron trifluoride etherate, to bis(1,5-cyclooctadiene)nickel(O) and triphenylphosphine. Support for a mechanism involving positively charged nickel complexes is presented. © 1979.

引用

页码：97 / 105

页数：9

共 11 条

[1] AKERMARK B, 1975, TETRAHEDRON LETT, P3733
[2] CHEMICAL BONDING AND REACTIVITY IN NICKEL-ETHENE COMPLEXES - ABINITIO MO-SCF STUDY
AKERMARK, B
ALMEMARK, M
ALMLOF, J
BACKVALL, JE
ROOS, B
STOGARD, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (14) : 4617 - 4624
[3] REACTION OF AMINES WITH 1,3-DIENES CATALYZED BY NICKEL-COMPLEXES
BAKER, R
COOK, AH
HALLIDAY, DE
SMITH, TN
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (12): : 1511 - 1517
[4] BAKER R, 1973, TETRAHEDRON LETT, P503
[5] BAKER R, 1971, CHEM COMMUN, P1583
[6] NICKEL-CATALYZED REACTION OF BUTADIENE - FORMATION OF 2-METHYLENEVINYLCYCLOPENTANE AND ADDITION OF AMINE TO BUTADIENE
FURUKAWA, J
KIJI, J
MITANI, SI
YOSHIKAWA, S
YAMAMOTO, K
SASAKAWA, E
[J]. CHEMISTRY LETTERS, 1972, (12) : 1211 - 1212
[7] HEIMBACH P, 1968, ANGEW CHEM, V80, P967
[8] KIJI J, 1973, CHEM COMMUN, P770
[9] Kiji J., 1974, J ORGANOMET CHEM, V77, P125
[10] ROSE D, 1972, TETRAHEDRON LETT, P4197

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