RETRO-DIELS-ALDER REACTION INDUCED BY PI,PI' EXCITATION AND BY ELECTRON IMPACT

被引：18

作者：

NOZAKI, H

KATO, H

NOYORI, R

机构：

[1] Department of Industrial Chemistry, Kyôto University, Kyôto

[2] Department of Chemistry, Nagoya University, Nagoya

来源：

TETRAHEDRON | 1969年 / 25卷 / 08期

关键词：

D O I：

10.1016/S0040-4020(01)82739-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title photoreaction is observed upon irradiation of styrene- and indene-anthracene adducts giving anthracene photodimers, while other Diels-Alder adducts of anthracene are photostable. The dissociation is rationalized by assuming a stepwise mechanism involving a diradical intermediate. This behaviour shows that a close correlation exists between cation radicals produced on electron impact and π,π* excited species. © 1969.

引用

页码：1661 / &

共 22 条

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