TRANSITION METAL-CARBYNE COMPLEXES .55. SPONTANEOUS REARRANGEMENT OF A CARBENE- TO A CARBYNE COMPLEX - C,CR MIGRATION OF A SN(C6H5)3 GROUP

被引：26

作者：

FISCHER, EO

FISCHER, H

SCHUBERT, U

PARDY, RBA

机构：

[1] Anorganisch-chemisches Institut, Technischen Universität Müchen, Garching, D-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fresh light is thrown upon the rearrangements of carbene complexes into carbyne complexes by the spontaneous reaction (1) → (2). It is quantitative at room temperature, does not involve an ionic mechanism and refutes the idea that the migrating heteroatom X in (CO)5CrC(NEt2)X must have a lone pair. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：871 / 871

页数：1

共 5 条

[1] FISCHER EO, J ORGANOMET CHEM
[2] UNUSUAL SELECTIVITY IN THERMAL REARRANGEMENT ELIMINATION REACTION OF A CARBENE COMPLEX IN SOLUTION AND IN SOLID-STATE
FISCHER, H
MOTSCH, A
KLEINE, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (11): : 842 - 844
[3] FISCHER H, UNPUBLISHED
[4] FISCHER H, 1978, ANGEW CHEM, V90, P914
[5] TRANSITION-METAL CARBENE COMPLEXES .111. STRUCTURAL-ANALYSIS OF PENTACARBONYLDIETHYLAMINOCHLOROCARBENECHROMIUM
HUTTNER, G
FRANK, A
FISCHER, EO
KLEINE, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 141 (02) : C17 - C20

← 1 →