MICROWAVE SPECTROSCOPY OF PYROLYTICALLY PRODUCED, RAPIDLY ISOLATED TRANSIENT MOLECULES

被引：4

作者：

LEGON, AC

STEPHENSON, D

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 19期

关键词：

D O I：

10.1039/ft9918703325

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

P-31 Spin-rotation hyperfine splitting has been observed in the 1(01) <-- 0(00) transitions of CH2 = (PCl)-Cl-35 and CH2 = (PCl)-Cl-37 by pulsed-nozzle, FT microwave spectroscopy. The transient molecules CH2 = PCl were produced by using a pyrolysis nozzle and then isolated on the ca. 10-mu-s timescale.

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页码：3325 / 3326

页数：2

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