VOLUMETRIC BEHAVIOR OF 2-METHOXYETHANOL+1,2-DIMETHOXYETHANE BINARY-MIXTURES

被引：16

作者：

CORRADINI, F ^{[1
]}

MARCHETTI, A ^{[1
]}

TAGLIAZUCCHI, M ^{[1
]}

TASSI, L ^{[1
]}

机构：

[1] UNIV MODENA,DEPT CHEM,I-41100 MODENA,ITALY

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1994年 / 47卷 / 03期

关键词：

D O I：

10.1071/CH9940415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermodynamic interactions in 2-methoxyethanol (component 1)+1,2-dimethoxyethane (component 2) binary mixtures have been studied in terms of the excess molar volume from the densities, measured at 19 temperatures between -10 and 80-degrees-C, for nine binary mixtures covering the whole miscibility field expressed by the mole fraction 0 less-than-or-equal-to X1 less-than-or-equal-to 1. Excess molar volumes are discussed in terms of induced conformational changes in each component in the presence of the other. The present findings support a hypothesis about the formation of a solvent-cosolvent complex species which has a well defined 1:1 stoichiometric composition and is thermostable under the experimental conditions.

引用

页码：415 / 422

页数：8

共 19 条

[1]

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[2]

Byers W. H., 1939, J CHEM PHYS, V7, P175

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