SELECTIVE ELECTROCHEMICAL FORMYL HYDROGEN-EXCHANGE FLUORINATION OF ALIPHATIC-ALDEHYDES TO PREPARE ACYL FLUORIDES USING HF-BASE SOLUTIONS

被引：23

作者：

YONEDA, N

CHEN, SQ

HATAKEYAMA, T

HARA, S

FUKUHARA, T

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 05期

关键词：

D O I：

10.1246/cl.1994.849

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The selective displacement of formyl hydrogen (-(C=O)-H) to fluorine in aliphatic aldehydes was successfully carried out electrochemically to give acyl fluorides in base-nHF (base: pyridine or Et(3)N, n=3-6) electrolyte solution with or without solvents such as acetonitrile and sulfolane.

引用

页码：849 / 850

页数：2