IONIC PEROXIDE FRAGMENTATIONS

被引：9

作者：

DEYRUP, JA

MOYER, UV

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 06期

关键词：

D O I：

10.1021/jo01258a066

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of a-oxy acids with peroxy acids and N,Nʹ-dicyclohexylcarbodiimide yielded the expected diacyl peroxide only under carefully controlled conditions and then only when the α-oxy group was part of a three-membered ring. The reactions of these peroxides have been studied. Based largely on an examination of products, an ionic fragmentation mechanism has been proposed for their decompositions. © 1969, American Chemical Society. All rights reserved.

引用

页码：1835 / &

共 34 条

[1] A SERIES OF TERTIARY BUTYL PERESTERS SHOWING CONCERTED DECOMPOSITION
BARTLETT, PD
HIATT, RR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) : 1398 - 1405
[2] Oxidation of unsaturatred compounds. IV. Oxidation of crotonic acid with hypochlorous and perbenzoic acids
Braun, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 : 3185 - 3188
[3] SOLVOLYTIC REARRANGEMENT OF SOME 1,2-DIPHENYL-3,3-DICHLOROAZIRIDINES
BROOKS, RE
EDWARDS, JO
LEVEY, G
SMYTH, F
[J]. TETRAHEDRON, 1966, 22 (04) : 1279 - &
[4] A BOND ENERGY SCHEME .2. STRAIN AND CONJUGATION ENERGIES IN CYCLIC COMPOUNDS
COX, JD
[J]. TETRAHEDRON, 1963, 19 (07) : 1175 - &
[5] CURTIN DY, 1964, SYSTEMATIC IDENTIFIC, P256
[6] CURTIN DY, 1964, SYSTEMATIC IDENTIFIC, P229
[7] DAVIES AG, 1961, ORGANIC PEROXIDES, P64
[8] AN OXYGEN-18 TRACER STUDY OF THE REARRANGEMENT OF PARA-METHOXY-PARA'-NITROBENZOYL PEROXIDE
DENNEY, DB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (03) : 590 - 592
[9] DEGRADATION OF ACIDS TO ALCOHOLS BY CARBOXY-INVERSION REACTION
DENNEY, DB
SHERMAN, N
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (11) : 3760 - &
[10] CHEMISTRY OF CYCLOPROPANOLS
DEPUY, CH
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1968, 1 (02) : 33 - &

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