MOLECULAR-STRUCTURE OF THE ALKOXO-OXYGEN BRIDGED BINUCLEAR COPPER (II) COMPLEX, [CU2[(CH3)2N(CH2)3NH(CH2)2O]2(CH3OH)2](CLO4)2

被引：23

作者：

MATSUMOTO, N ^{[1
]}

KIDA, S ^{[1
]}

UEDA, I ^{[1
]}

机构：

[1] KYUSHU UNIV,COLL GEN EDUC,CHUO KU,FUKUOKA 810,JAPAN

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1979年 / 9卷 / 02期

关键词：

D O I：

10.1080/00958977908076517

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structure of the title compound has been determined from single-crystal X-ray diffraction methods. The molecule consists of an alkoxo-oxygen bridged dimeric unit, [Cu2 {(CH3)2 N(CH2)3 NH(CH2)20 }2 (CH3OH)2]2+, and two perchlorate anions as counter ions. The coordination geometry of each copper ion is a five coordinated tetragonal pyramid, of which the apical site is occupied by the oxygen atom of methanol. The magnetic moment of the compound is remarkably higher than that expected from Cu—O—Cu angle. This is explained in terms of the effect of axial coordination. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：133 / 137

页数：5

共 24 条

[1]

Bertrand J. A., 1970, INORG CHIM ACTA, V4, P203

[2] RELATION BETWEEN MAGNETIC, SPECTROSCOPIC, AND STRUCTURAL-PROPERTIES OF BIS[CHLORO(N-ISOPROPYL-2-HYDROXYBENZYLIDENE)AMINATO-MU-O-COPPER(II)] AND BIS(N-ISOPROPYL-2-HYDROXYBENZYLIDENEAMINATO)COPPER(II) [J].