SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND REACTIONS OF [PDPHCL(2,9-DIMETHYL-1-10-PHENANTHROLINE)] WITH OLEFINS

被引：19

作者：

CUCCIOLITO, ME ^{[1
]}

DERENZI, A ^{[1
]}

GIORDANO, F ^{[1
]}

RUFFO, F ^{[1
]}

机构：

[1] UNIV NAPLES FEDERICO II,DIPARTIMENTO CHIM,I-80134 NAPLES,ITALY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 11期

关键词：

D O I：

10.1021/om00011a068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dichlorodiphenyllead(IV) acts, through an oxidative-addition process, as a phenylating reagent on [Pd(N,N-chelate)(olefin)] substrates. The previously unknown [PdPhCl(dmphen)] (dmphen 2,9-dimethyl-1,10-phenanthroline) compound has been synthesized and characterized by an X-ray structural analysis. The reactions of this complex and of its related cationic species [PdPh(dmphen)(MeCN)](+) with ethylene and propene have also been studied.

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页码：5410 / 5414

页数：5

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