REVERSIBLE PHOTOISOMERIZATION OF KETENE TO ETHYNOL

被引：36

作者：

HOCHSTRASSER, R ^{[1
]}

WIRZ, J ^{[1
]}

机构：

[1] UNIV BASEL,INST PHYS CHEM,KLINGELBERGSTR 80,CH-4056 BASEL,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 04期

关键词：

D O I：

10.1002/anie.199004111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ketene decomposes under gas‐phase irradiation to give CO and CH2. By contrast, irradiation at 308 nm in an argon matrix results exclusively in the high energy tautomer ethynol, whose isolation in pure argon in this way was achieved for the first time. The reaction can be reversed by short wavelength UV photolysis. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：411 / 413

页数：3

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