RETRO AZA DIELS-ALDER REACTIONS OF 2-AZANORBORNENES - IMPROVED METHODS FOR THE UNMASKING OF PRIMARY AMINES

被引：24

作者：

GRIECO, PA

CLARK, JD

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 08期

关键词：

D O I：

10.1021/jo00295a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The unmasking of primary amines via the heterocycloreversion of N-alkyl-2-azanorbornenes can be catalyzed by either copper(II) or a sulfonic acid based ion exchange resin which obviates the necessity of employing a reactive dienophile to trap the cyclopentadiene as it is produced. © 1990, American Chemical Society. All rights reserved.

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页码：2271 / 2272

页数：2

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