ELECTRICAL AND THERMAL STUDIES ON COPPER-COMPLEXES OF PHTHALOCYANINE AND BIPHTHALOCYANINE AND THEIR DERIVATIVES

被引：18

作者：

ELSHEREAFY, E ^{[1
]}

ELGHAFFAR, MAA ^{[1
]}

机构：

[1] NATL RES CTR,DEPT POLYMER & PIGMENT,CAIRO,EGYPT

来源：

THERMOCHIMICA ACTA | 1991年 / 186卷 / 02期

关键词：

D O I：

10.1016/0040-6031(91)87034-T

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The electrical and thermal behaviour of metal-free biphthalocyanine and its Cu complex, and of phthalocyanine Cu complex were examined. The effect of chloro and carboxylic substitution was evaluated. The compounds show semiconductivity in the range 278-573 K. The activation energy for conduction was calculated and a conduction mechanism was proposed. The activation energy of the alpha --> beta-phase transformation for some compounds was calculated using DTA. Decarboxylation was observed in both d.c. electrical conductivity and DTA measurements.

引用

页码：179 / 185

页数：7

共 12 条

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[2]

ABDELGHAFFAR MA, IN PRESS THERMOCHIM

[3]

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[4]

ABOUSEKKINA MM, 1989, REACT SOLID, V7, P219, DOI 10.1016/0168-7336(89)80038-5