DIRECT SYNTHESIS OF ACETALS BY RHODIUM-CATALYZED HYDROFORMYLATION OF ALKENES IN THE PRESENCE OF ORTHOFORMATE

被引：41

作者：

SOULANTICA, K

SIROL, S

KOINIS, S

PNEUMATIKAKIS, G

KALCK, P

机构：

[1] UNIV ATHENS,DEPT INORGAN CHEM,GR-15771 ATHENS,GREECE

[2] ECOLE NATL SUPER CHIM TOULOUSE,CATALYSE & CHIM FINE LAB,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 498卷 / 01期

关键词：

HYDROFORMYLATION; RHODIUM; CATALYSIS; ACETALS;

D O I：

10.1016/0022-328X(95)05594-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The two catalyst precursors [Rh-2(mu-penicillamine)(2)(CO)(4)][OTf](2) and [Rh-2(mu-cysteine)(2)(CO)(4)][OTf](2) in the presence of 4 equivalents of P(OPh)(3) in triethyl orthoformate as solvent and reactant, permit the low pressure hydroformylation of various alkenes into the corresponding acetals. Apart from a few low-yield by-products resulting from isomerization of the substrates, the carbonylated products obtained directly and exclusively are acetals.

引用

页码：C10 / C13

页数：4

共 11 条

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