GROWING CHAIN ISOMERIZATIONS IN METALLOCENE-CATALYZED ZIEGLER-NATTA 1-ALKENE POLYMERIZATION

被引：48

作者：

BUSICO, V

CIPULLO, R

机构：

[1] Dipartimento di Chimica, Università di Napoli Federico II, I-80134 Napoli, Via Mezzocannone

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 497卷 / 1-2期

关键词：

ZIEGLER-NATTA CATALYSTS; ISOMERIZATION; POLYMERIZATION;

D O I：

10.1016/0022-328X(95)00101-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of isomerization reactions of the growing polymer chain have been shown to compete with the process of 1-alkene polyinsertion promoted by Group 4 metallocene Ziegler-Natta catalysts. The consequences of such reactions on the regioregularity and stereoregularity of the polymers are discussed for the class of isotactic-specific C-2-symmetric metallocene catalysts.

引用

页码：113 / 118

页数：6

共 26 条

[1] MICROSTRUCTURE OF POLY(1-HEXENE) PRODUCED BY ANSA-ZIRCONOCENIUM CATALYSIS [J].