SPECTRA OF CHI(3)(-3-OMEGA-OMEGA, OMEGA, OMEGA) IN POLY(2,5-DIMETHOXY PARA-PHENYLENE VINYLENE) (MO-PPV) FOR VARIOUS CONVERSION LEVELS

被引：17

作者：

KURIHARA, T ^{[1
]}

MORI, Y ^{[1
]}

KAINO, T ^{[1
]}

MURATA, H ^{[1
]}

TAKADA, N ^{[1
]}

TSUTSUI, T ^{[1
]}

SAITO, S ^{[1
]}

机构：

[1] KYUSHU UNIV, DEPT MAT SCI & TECHNOL, KASUGA, FUKUOKA 816, JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 183卷 / 06期

关键词：

D O I：

10.1016/0009-2614(91)80171-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chi-(3) spectra of MO-PPV films for various conversion levels were measured for the first time. It has been demonstrated clearly that the intensities of chi-(3) increase corresponding to elongation of pi-conjugation lengths. Especially, chi-(3) increases significantly at the final conversion level in which long rigid pi-conjugated sequences are formed. The corrected chi-(3) value reaches 1.6 x 10(-10) esu where the three-photon resonance seemed to play an important role. It is predicted that there is a certain dominant resonant level effective to large chi-(3), which is possibly resulted from the distribution of a long rigid pi-conjugation.

引用

页码：534 / 538

页数：5

共 23 条

[1]

ANTOUN S, 1986, POLYM SCI POLYM PE, V24, P2793

[2] 3RD HARMONIC-GENERATION IN PRECURSOR ROUTE POLY(PARA-PHENYLENE VINYLENE) [J].

BRADLEY, DDC ;

MORI, Y .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1989, 28 (02) :174-177

[3] PRECURSOR-ROUTE POLY(P-PHENYLENEVINYLENE) - POLYMER CHARACTERIZATION AND CONTROL OF ELECTRONIC-PROPERTIES [J].

BRADLEY, DDC .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1389-1410

[4] THE ELECTRONIC AND ELECTROCHEMICAL PROPERTIES OF POLY(PHENYLENE VINYLENES) AND POLY(THIENYLENE VINYLENES) - AN EXPERIMENTAL AND THEORETICAL-STUDY [J].

ECKHARDT, H ;

SHACKLETTE, LW ;

JEN, KY ;

ELSENBAUMER, RL .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (02) :1303-1315

[5] HIGHLY-CONDUCTING, POLY(2,5-THIENYLENE VINYLENE) PREPARED VIA A SOLUBLE PRECURSOR POLYMER [J].

JEN, KY ;

MAXFIELD, M ;

SHACKLETTE, LW ;

ELSENBAUMER, RL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :309-311

[6] OPTICAL 3RD-HARMONIC GENERATION FROM POLY(2,5-THIENYLENE VINYLENE) THIN-FILMS [J].

KAINO, T ;

KUBODERA, K ;

KOBAYASHI, H ;

KURIHARA, T ;

SAITO, S ;

TSUTSUI, T ;

TOKITO, S ;

MURATA, H .

APPLIED PHYSICS LETTERS, 1988, 53 (21) :2002-2004

[7] OPTICAL 3RD-HARMONIC GENERATION FROM POLY(PARA-PHENYLENEVINYLENE) THIN-FILMS [J].

KAINO, T ;

KUBODERA, KL ;

TOMARU, S ;

KURIHARA, T ;

SAITO, S ;

TSUTSUI, T ;

TOKITO, S .

ELECTRONICS LETTERS, 1987, 23 (20) :1095-1097

[8] OPTICAL 3RD-HARMONIC GENERATION FROM POLY-(2,5-DIMETHOXY PARA-PHENYLENE VINYLENE) THIN-FILM [J].

KAINO, T ;

KOBAYASHI, H ;

KUBODERA, K ;

KURIHARA, T ;

SAITO, S ;

TSUTSUI, T ;

TOKITO, S .

APPLIED PHYSICS LETTERS, 1989, 54 (17) :1619-1621

[9] NONLINEAR OPTICAL-PROPERTIES OF HIGHLY ORIENTED POLYDIACETYLENE EVAPORATED-FILMS [J].

KANETAKE, T ;

ISHIKAWA, K ;

HASEGAWA, T ;

KODA, T ;

TAKEDA, K ;

HASEGAWA, M ;

KUBODERA, K ;

KOBAYASHI, H .

APPLIED PHYSICS LETTERS, 1989, 54 (23) :2287-2289

[10]

KOBAYASHI H, 1989, 36TH P SPRING M JAP

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