SYNTHESIS AND STRUCTURE OF (ACETATO-O,O')(PERCHLORATO-O)(2,2'/6'2''-TERPYRIDINE-N,N',N'')COPPER(II)

被引：4

作者：

MUNOZ, MC

RUIZ, R

JULVE, M

LLORET, F

SOLANS, X

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM INORGAN,E-46100 BURJASSOT,SPAIN

[2] UNIV BARDELONA,DEPT CRISTALOG MINERAL & DIPOSITS MINERALS,E-08028 BARCELONA,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192004505

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Acetato-O,O')(perchlorato-O)(2,2':6',2''-terpyridine-N,N',N'')copper(II), [Cu(ClO4)(CH3-CO2)(C15H11N3)], M(r) = 455.32, triclinic, P1BAR, a = 11.010 (3), b = 10.791 (3), c = 8.356 (2) angstrom, alpha = 83.56 (2), beta = 86.11 (2), gamma = 64.67 (2)degrees, V = 891.4 (7) angstrom3, Z = 2, D(x) = 1.696 g cm-3, lambda(Mo Kalpha) = 0.71069 angstrom, mu = 14.66 cm-1, F(000) = 462, T = 298 K, final R = 0.062 and wR = 0.066 for 1011 reflections with I greater-than-or-equal-to 2.5sigma(I). The structure consists of discrete neutral [Cu(terpy)(CH3COO)(ClO4)] units (terpy = 2,2':6',2''-terpyridine). The coordination environment around Cu'' ions is distorted 4 + 2 octahedral. The equatorial plane is composed of the three N atoms of the terpyridine ligand and one O atom of the acetate group, whereas the apical positions are occupied by the other O atom of the acetate ligand and one O atom of the perchlorate anion.

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页码：674 / 677

页数：4

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