SELECTIVE HYDROGENOLYSIS OF CFC-113A BY GROUP-VIII TRANSITION-METAL COMPLEXES

被引：12

作者：

CHO, OJ

LEE, IM

PARK, KY

KIM, HS

机构：

[1] INHA UNIV,DEPT CHEM,INCHON 402751,SOUTH KOREA

[2] KOREA ADV INST SCI & TECHNOL,CTR ALTERNAT TECHNOL,CFC,SEOUL,SOUTH KOREA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 71卷 / 01期

关键词：

SELECTIVE HYDROGENOLYSIS; CFC-113A; GROUP VIII TRANSITION METAL COMPLEXES; CATALYSIS; SELECTIVITY;

D O I：

10.1016/0022-1139(94)03159-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Highly efficient and selective hydrogenolysis of CFC-113a (CF3CCl3) to produce HCFC-123 (CF3CHCl2) has been achieved through the use of Group VIII transition metal complexes. The catalytic activity observed was sensitive to solvents and to the structures of the metal complexes.

引用

页码：107 / 109

页数：3

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[3]

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