ABSORPTION SPECTRA IN FAR INFARED OF 7 ANHYDROUS AND HYDRATED HALIDES . BA CL2 BABR2 SRBR2 SRCL2 PBCL2 PBBR2 AND NAI

被引：15

作者：

HADNI, A

MORLOT, G

BREHAT, F

机构：

[1] Université de Nancy, Nancy

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 08期

关键词：

D O I：

10.1016/0584-8539(68)80137-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

When anhydrous, crystals of nine inorganic chlorides, bromides and iodides exhibit three absorption bands in the far infra-red. When hydrated, it has been possible by deuteration to differentiate between: 1.(1) Several absorption bands mainly related to water molecules: -one perturbed valence vibration ○ -two angular vibrations ○ -three librations around the three principal molecular axis of inertia ○ -six translational vibrations. 2. (2) Two low frequency absorption bands not sensitive to deuteration, which are related to motions involving mainly the heaviest atoms of the unit cell. © 1968.

引用

页码：1167 / &