PHOTOCHEMICALLY INDUCED [2+2]-CYCLOADDITIONS OF ALKENES AND DIENES TO THE S-S BOND OF THE NIDO-CLUSTER [(CO)3FES]2

被引：24

作者：

KRAMER, A ^{[1
]}

LORENZ, IP ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST ANORGAN CHEM,MORGENSTELLE 18,W-7400 TUBINGEN 1,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 388卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)85361-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkenes 1-pentene and 2-pentene and the dienes 1,3-butadiene and 1,4-pentadiene are inserted into the SS-bond of the nido-cluster [(CO)3FeS]2 (1) by photochemically induced [2 + 2]-cycloaddition. The differently functionalized 1,2-ethanedithiolato ligands that result can act as chelating and μ2-bridging ligands to the Fe2(CO)6-complex fragment. The novel complexes 2-5 have been characterized by IR, 1H and 13C[1H] NMR and mass spectroscopy. © 1989.

引用

页码：187 / 193

页数：7

共 23 条

[1] SYNTHESIS OF HETEROMETALLIC CLUSTER COMPOUNDS FROM FE3(MU-3-TE)2(CO)9 AND COMPARISONS WITH ANALOGOUS SULFIDE CLUSTERS
BOGAN, LE
LESCH, DA
RAUCHFUSS, TB
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) : 429 - 438
[2] A NEW TYPE OF IRON-MOLYBDENUM-SULFUR CLUSTER - SYNTHESIS AND STRUCTURE OF [FE2MO2(ETA-5-C5H5)2(MU-3-S)2(MU-3-CO)2(CO)6]
BRAUNSTEIN, P
JUD, JM
TIRIPICCHIO, A
TIRIPICCHIOCAMELLINI, M
SAPPA, E
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (04): : 307 - 308
[3] BRAUNSTEIN P, 1982, ANGEW CHEM, V94, P3188
[4] BREITMEIER E, 1978, ORGANISCHE CHEM, V1, P561
[5] CHEMISTRY OF (MU-DITHIO)BIS(TRICARBONYLIRON), AN INORGANIC MIMIC OF ORGANIC DISULFIDES .3. REACTION WITH LOW-VALENT METAL-COMPOUNDS AND SOME INTERESTING ISOLOBAL ANALOGIES INVOLVING THE PRODUCTS
COWIE, M
DEKOCK, RL
WAGENMAKER, TR
SEYFERTH, D
HENDERSON, RS
GALLAGHER, MK
[J]. ORGANOMETALLICS, 1989, 8 (01) : 119 - 132
[6] THE NATURE OF THE LUMO IN FE2(CO)6S2 AND THE BONDING IN FE2(CO)6S22-
DEKOCK, RL
BAERENDS, EJ
HENGELMOLEN, R
[J]. ORGANOMETALLICS, 1984, 3 (02) : 289 - 292
[7] ZUR KENNTNIS DES KOMPLEXCHEMISCHEN VERHALTENS VON SCHWEFEL-HALTIGEN UND SELEN-HALTIGEN EISENCARBONYL-VERBINDUNGEN
HIEBER, W
ZEIDLER, A
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1964, 329 (1-6): : 92 - 101
[8] KATTAB SA, 1964, J ORGANOMET CHEM, V1, P373
[9] INSERTION REACTIONS OF ETHENE AND CARBON-MONOXIDE IN THE S-S BONDING OF [(CO)3FES]2 NIDO-CLUSTERS AND SYNTHESIS AND STRUCTURE OF THE 1,3-ETHANESULFENATOTHIOLATO COMPLEX, [(CO)3FE]2SC2H4S(O)
MESSELHAUSER, J
GUTENSOHN, KU
LORENZ, IP
HILLER, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 321 (03) : 377 - 388
[10] MESSELHAUSER J, 1985, Z NATURFORSCH B, V40, P1064

← 1 2 3 →