HYDROLYSIS OF AMIDES - STERIC EFFECTS ON KINETICS AND MECHANISM OF THE BASIC HYDROLYSIS OF N-ACYLCARBAZOLES

被引：10

作者：

CIPICIANI, A

LINDA, P

SAVELLI, G

机构：

[1] Dipartimento di Chimica, Universita di Perugia, Perugia

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1979年 / 16卷 / 04期

关键词：

D O I：

10.1002/jhet.5570160412

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The hydroxide ion catalyzed hydrolysis of a series of N‐acylcarbazoles has been studied in water at 25°. Both the rate constants of formation of the tetrahedral intermediate and of its collapse to products are strongly increased by alkyl group branching in the acyl portion. Copyright © 1979 Journal of Heterocyclic Chemistry

引用

页码：677 / 678

页数：2

共 7 条

[1]

Bruylants A., 1960, REC CHEM PROGR, V21, P213

[2]

CIPICIANI A, J CHEM SOC P2

[3] The influence of alkyl groups upon reaction velocities in solution Part IV The alkaline and acid hydrolyses of the ethyl esters of the lower saturated aliphatic acids in aqueous acetone [J].