POLYMER SOLID ELECTROLYTES BASED ON ETHYLENE-OXIDE COPOLYMERS

被引：18

作者：

FLORJANCZYK, Z ^{[1
]}

KRAWIEC, W ^{[1
]}

WIECZOREK, W ^{[1
]}

PRZYLUSKI, J ^{[1
]}

机构：

[1] TECH UNIV WARSAW,INST INORGAN TECHNOL,PL-00664 WARSAW,POLAND

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1991年 / 187卷

关键词：

D O I：

10.1002/apmc.1991.051870103

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ethylene oxide was copolymerized with propylene oxide, epichlorohydrin or styrene oxide at various monomer feed compositions, using partially hydrolyzed organoaluminium compounds as catalysts. The copolymers obtained after doping with NaI form highly conductive polymeric electrolytes. Complex impedance measurements show relaxation semicircles much less depressed than in semicrystalline electrolytes based on poly(ethylene oxide). The maximum values of the room temperature conductivity for each kind of copolymer containing electrolytes are higher than those for the pristine poly(ethylene oxide)-NaI system. The highest value, equal to 2.6.10(-5) S/cm at 25-degrees-C, was found for poly(ethylene oxide-co-propylene oxide) containing 33 mol-% of propylene oxide monomeric units.

引用

页码：19 / 32

页数：14

共 12 条

[1]

ARMAND MB, 1987, 6 INT C SOL STAT ION

[2] POLY(ALKYLENE OXIDE) IONOMERS .7. USE OF TRIETHYLALUMINUM WATER ACETYLACETONE (1.0-0.5-1.0) FOR THE POLYMERIZATION OF OXIRANES [J].

BANSLEBEN, DA ;

HERSMAN, MJ ;

VOGL, O .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (10) :2489-2500

[3] MICROSCOPIC INVESTIGATION OF IONIC-CONDUCTIVITY IN ALKALI-METAL SALTS POLY(ETHYLENE OXIDE) ADDUCTS [J].

BERTHIER, C ;

GORECKI, W ;

MINIER, M ;

ARMAND, MB ;

CHABAGNO, JM ;

RIGAUD, P .

SOLID STATE IONICS, 1983, 11 (01) :91-95

[4]

KELLY J, 1979, POLYMER, V20, P1048, DOI 10.1016/0032-3861(79)90287-8

[5]

LINDEN E, 1987, SOLID STATE IONICS, V28, P994

[6]

NICHOLAS CV, 1987, JUN P INT S POL EL S

[7]

PASSINIEMI P, 1987, SOLID STAT IONICS, V28, P1001

[8] GLASS-TRANSITION AND CHAIN FLEXIBILITY OF LINEAR POLYMERS [J].

PRIVALKO, VP ;

LIPATOV, YS .

JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1974, B 9 (03) :551-564

[9]

STASINSKI J, 1982, POLIMERY WARSAW, V27, P204

[10]

STILLE JK, 1967, J POLYM SCI A1, V5, P2033

← 1 2 →