ELECTRODEPOSITION OF CADMIUM FROM NON-AQUEOUS SOLUTIONS .3. DEPOSITION FROM CDI2-(CNH2N+1)4NI-DIMETHYLFORMAMIDE SYSTEMS

被引：2

作者：

MENZIES, IA

WHITE, BS

机构：

[1] Corrosion Laboratories, Department of Chemical Engineering, University of Manchester Institute of Science and Technology, Manchester 1, England

来源：

ELECTROCHIMICA ACTA | 1969年 / 14卷 / 05期

关键词：

D O I：

10.1016/0013-4686(69)80017-4

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A study of the electrodeposition of cadmium from solutions of CdI2-tetra-alkylammonium-iodides-ethylformamide has been made. At low cds substrate-oriented deposits are formed in [(C4H9)4N]2CdI4-dimethylformamide solutions; above a critical cd, which increases from ca 20 to 45 mA/cm2 with increasing temperature from 18 to 45°C but is independent of concentration, random microcrystalline deposits are obtained. Uniform, adherent, randomly oriented microcrystalline deposits up to 120 μm thick can be obtained under optimum conditions. Under galvanostatic conditions, the first 500-1000 Å of metal deposited in 0·4 M [(C4H9)4N]2CdI4-dimethylformamide solutions at 25 mA/cm2 at 25°C are substrate-oriented. A transition stage at 1000-2000 Å thickness leads to random microcrystalline growth of small (0·1-0·15 μm dia) crystals. Although moderately, satisfactory microcrystalline coatings of limited thickness can be obtained from the CdI2-tetra-heptylammonium-iodide-dimethylformamide system, deposits from both this system and the corresponding tetrahexylammonium iodide system are in general powdery and unsatisfactory. © 1969.

引用

页码：413 / &

共 11 条

[1]

Barnes S.C., 1960, ELECTROCHIM ACTA, V2, P195, DOI [10.1016/0013-4686(60)87018-1, DOI 10.1016/0013-4686(60)87018-1]

[2]

COCHRANE W, 1936, P PHYS SOC LONDON, V28, P723

[3]

EMBURY JD, 1966, ELECTROCHIM ACTA, V11, P1491

[4] An electron-diffraction study of the structure of electro-deposited metals. [J].

Finch, GI ;

Sun, CH .

TRANSACTIONS OF THE FARADAY SOCIETY, 1936, 32 (01) :0852-0863

[5]

FINCH GI, 1947, DISCUSS FARADAY SOC, P144

[6] DOUBLE COUCHE ELECTROCHIMIQUE ET CINETIQUE DES REACTIONS DELECTRODE - ELUCIDATION DU MODE DACTION DES CATIONS TETRAALKYLAMMONIUM [J].

GIERST, L ;

TONDEUR, J ;

NICOLAS, E .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1965, 10 (5-6) :397-&

[7]

MENZIES IA, 1967, T I METAL FINISHING, V45, P181

[8]

MENZIES IA, 1968, T I METAL FINISH, V46, P65

[9]

SETTY THV, 1935, T FARADAY SOC, V51, P984

[10]

STORY GS, 1960, T I MET FINISH, V37, P11

← 1 2 →