MICROWAVE SPECTROSCOPY OF OH- IONS IN KCL AND NACL LATTICES

被引：29

作者：

SCOTT, RS

FLYGARE, WH

机构：

[1] Materials Research Laboratory and Noyes Chemical Laboratory, University of Illinois, Urbana

来源：

PHYSICAL REVIEW | 1969年 / 182卷 / 02期

关键词：

D O I：

10.1103/PhysRev.182.445

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Microwave resonant absorption has been observed in OH - doped KCl and NaCl crystals. Several lines were observed from 8-40 GHz by using relatively standard microwave spectroscopic techniques. The zero-field spectra obtained here indicate that the OH- ion experiences a strong C4v potential in addition to the expected octahedral crystal field. The C4v potential probably arises from a shift of the OH- center of mass from the lattice site. © 1969 The American Physical Society.

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页码：445 / &

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