SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF BINUCLEAR RHODIUM AND RUTHENIUM COMPLEXES WITH 1,8-NAPHTHYRIDINE-2,7-DICARBOXYLATE - X-RAY MOLECULAR-STRUCTURE OF TRIS(MU-ACETATO)(1,8-NAPHTHYRIDINE-2,7-DICARBOXYLATO)DIRUTHENIUM

被引：54

作者：

COLLIN, JP

JOUAITI, A

SAUVAGE, JP

KASKA, WC

MCLOUGHLIN, MA

KEDER, NL

HARRISON, WTA

STUCKY, GD

机构：

[1] INST CHIM,CHIM ORGANOMINERAL LAB,CNRS,UA 422,1 RUE BLAISE PASCAL,F-67000 STRASBOURG,FRANCE

[2] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1021/ic00337a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cresent-shaped ligand 1,8-naphthyridine-2,7-dicarboxylate (dcnp2−) has been synthesized and treated with [Rh2(OAc)4] and [Ru2(OAc)4]Cl to give [Rh2(OAc)3(dcnp)]− and [Ru2(OAc)3(dcnp)], respectively, The mixed-valence state RuIII-RuII is highly stabilized by dcnp2− with a Kc value of 2.5 × 1024. The X-ray molecular structure of Ru2(O2C2H3)3(C10H9O4N2) was determined in the orthorhombic space group Pnam with a = 16.013 (2) Å, b = 20.792 (3) Å, c = 23.264 (3) Å, and Z = 12 and shows a pair of ruthenium atoms 2.265 (5) Å apart that are surrounded by three acetate bridges. The trans effect of the Ru-Ru bond causes a lengthening of the Ru-O dcnp bond in the complex. © 1990, American Chemical Society. All rights reserved.

引用

页码：2238 / 2241

页数：4

共 38 条

[1] SYNTHESIS AND STRUCTURE OF HEXAAQUANICKEL(II) TRIS(1,8-NAPHTHYRIDINE-2,7-DICARBOXYLATO)DINICKELATE(II) PENTAHYDRATE [J].