SYNTHESIS, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF PERIODATE COMPLEXES OF IRON(III)

被引：6

作者：

JONES, EM

LEVASON, W

OLDROYD, RD

WEBSTER, M

THOMAS, M

HUTCHINGS, J

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

[2] UNIV LIVERPOOL,DEPT PHYS,OLIVER LODGE LAB,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 20期

关键词：

D O I：

10.1039/dt9950003367

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Fe(NO3)(3) . 9H(2)O with NalO(4) in aqueous acid solution gave brown [Fe(4)l(3)O(24)H(15)] and subsequent reaction with concentrated alkalis formed M(n)[Fe(4)l(3)O(24)H(15-n)] (M = Li, Na, Kr Rb or Cs). The crystal structure of K6Na2[Fe(4)l(3)O(24)H(7)]. 14H(2)O has been determined and shown to contain an Anderson-type anion composed of seven edge-linked octahedra. In the crystal, studied a central FeO6 group is surrounded by six disordered FeO6 and IO6 groups. All the prepared salts have been shown to contain a similar anion based upon spectroscopic data. iron and iodine K-edge extended X-ray absorption fine structure data, and the Fe-57 Mossbauer spectra.

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页码：3367 / 3373

页数：7

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