FACILE SYNTHESIS OF S-ALKYL THIOCARBAMATES THROUGH REACTION OF CARBAMOYL LITHIUM WITH ELEMENTAL SULFUR

被引：76

作者：

MIZUNO, T

NISHIGUCHI, I

OKUSHI, T

HIRASHIMA, T

机构：

[1] Osaka Municipal Technical Research Institute, Joto-ku, Osaka, 536, 1-6-50, Morinomiya

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 47期

关键词：

D O I：

10.1016/0040-4039(91)80428-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Efficient synthesis of S-alkyl thiocarbamates was developed. The key step of this synthetic method is a conversion of carbamoyl lithium, generated from lithium dialkylamide and carbon monoxide, to lithium thiocarbamate by addition of elemental sulfur.

引用

页码：6867 / 6868

页数：2

共 11 条

[1]

Chin-Hsien W., 1981, SYNTHESIS-STUTTGART, P622

[2]

GRISLEY DW, 1961, J ORG CHEM, V26, P3568

[3] INSERTION OF CARBON-MONOXIDE INTO LITHIUM NITROGEN BONDS - ONE-POT SYNTHESIS OF DIALKYLFORMAMIDES AND DIALKYLGLYOXYLAMIDES [J].