BAND-STRUCTURE ENHANCEMENT OF THE INDIRECT FORBIDDEN TRANSITIONS

被引:7
作者
CAMASSEL, J
PASCUAL, J
MATHIEU, H
机构
[1] Centre d'Etudes d'Electronique des Solides, Université des Sciences et Techniques du Languedoc
来源
PHYSICAL REVIEW B | 1979年 / 20卷 / 12期
关键词
D O I
10.1103/PhysRevB.20.5292
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present an experimental investigation of the resonant enhancement of the indirect forbidden transitions near a direct-indirect crossover. Near-resonance conditions have been achieved in TiO2 by tuning the relative energy positions of a direct forbidden gap (3.031 eV) with respect to an indirect one (3.049 eV). We find a band-structure enhancement of the indirect absorption strength when crossing the direct-forbidden gap. The quantitative details of the experiment can be satisfactorily accounted for by a simple model which includes (i) the stress-induced breaking of the selection rules and (ii) the resonance effect. Uniaxial compressions up to 24 kbars in [100] direction have been found necessary to tune the band gaps. © 1979 The American Physical Society.
引用
收藏
页码:5292 / 5296
页数:5
相关论文
共 11 条
[1]   ELECTRONIC BAND-STRUCTURE OF TITANIUM-DIOXIDE [J].
DAUDE, N ;
GOUT, C ;
JOUANIN, C .
PHYSICAL REVIEW B, 1977, 15 (06) :3229-3235
[2]  
DJEVAHIRDJIAN SA, 1870, MONTHEY
[3]  
ELLIOTT RJ, 1957, PHYS REV, V108, P1834
[4]  
JORDAN JP, UNPUBLISHED
[5]   DIRECT STUDY OF NATURE OF NITROGEN BOUND-STATES IN GAAS1-XPX-N [J].
KLEIMAN, GG ;
NELSON, RJ ;
HOLONYAK, N ;
COLEMAN, JJ .
PHYSICAL REVIEW LETTERS, 1976, 37 (06) :375-378
[6]   LUMINESCENCE AND DIRECT EXPERIMENTAL-OBSERVATIONS OF BAND-STRUCTURE EFFECTS IN NITROGEN-DOPED GAXIN1-XP ALLOYS [J].
MARIETTE, H ;
CHEVALLIER, J .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (03) :1200-1205
[7]   UNIAXIAL STRESS DEPENDENCE OF THE DIRECT-FORBIDDEN AND INDIRECT-ALLOWED TRANSITIONS OF TIO2 [J].
MATHIEU, H ;
PASCUAL, J ;
CAMASSEL, J .
PHYSICAL REVIEW B, 1978, 18 (12) :6920-6929
[8]  
MATHIEU H, 1976, 13TH P INT C PHYS SE
[9]   FINE-STRUCTURE IN THE INTRINSIC ABSORPTION-EDGE OF TIO2 [J].
PASCUAL, J ;
CAMASSEL, J ;
MATHIEU, H .
PHYSICAL REVIEW B, 1978, 18 (10) :5606-5614
[10]   RESOLVED QUADRUPOLAR TRANSITION IN TIO2 [J].
PASCUAL, J ;
CAMASSEL, J ;
MATHIEU, H .
PHYSICAL REVIEW LETTERS, 1977, 39 (23) :1490-1493