COMPLEXES OF TRI-PROTONATED AND TETRA-PROTONATED FORMS OF 1,4,8,12-TETRAAZACYCLOPENTADECANE WITH CHLORIDE, NITRATE, IODATE, AND SULFATE-IONS IN AQUEOUS-MEDIA .2. ANALYSIS OF THE UNDERLYING EXPERIMENTAL AND THEORETICAL ASSUMPTIONS

被引：3

作者：

ALPER, JS ^{[1
]}

GELB, RI ^{[1
]}

SCHWARTZ, MH ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS,DEPT CHEM,HARBOR CAMPUS,BOSTON,MA 02125

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1991年 / 11卷 / 04期

关键词：

TETRAAZACYCLOPENTADECANE; MACROCYCLIC POLYAMINE; ANION COMPLEXATION;

D O I：

10.1007/BF01041413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a previous paper [1] the complexation behavior of 1,4,8,12-tetraazacyclopentadecane with various anions was studied. This analysis depended on various assumptions involving the accuracy and the interpretation of the experimental data. In this paper these assumptions are examined using pH potentiometry, C-13 NMR, and conductometric techniques. The validity of each of the assumptions was confirmed.

引用

页码：349 / 360

页数：12

共 5 条

[1] COMPLEXES OF TRI-PROTONATED AND TETRA-PROTONATED FORMS OF 1,4,8,12-TETRAAZACYCLOPENTADECANE WITH CHLORIDE, NITRATE, IODATE, AND SULFATE-IONS IN AQUEOUS-MEDIA .1. FORMATION-CONSTANTS, THERMODYNAMIC PROPERTIES, AND BONDING MECHANISMS
ALPER, JS
GELB, RI
SCHWARTZ, MH
[J]. JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1991, 11 (04): : 333 - 348
[2] HEXACYCLEN COMPLEXES OF SULFATE ANION
GELB, RI
SCHWARTZ, LM
ZOMPA, LJ
[J]. INORGANIC CHEMISTRY, 1986, 25 (10) : 1527 - 1535
[3] SOLUTION CHEMISTRY OF MACROCYCLES .1. BASICITY CONSTANTS OF "1,4,8,11-TETRA-AZACYCLOTETRADECANE, "1,4,8,12-TETRA-AZACYCLOPENTADECANE, AND 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE
MICHELONI, M
SABATINI, A
PAOLETTI, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (08): : 828 - 830
[4] EQUILIBRIUM STUDIES OF POLYNUCLEATING LIGANDS .2. METAL COMPLEXES OF TETRAKIS(AMINOMETHYL)METHANE
ZOMPA, LJ
BOGUCKI, RF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (17) : 4569 - &
[5] ZOMPA LJ, 1966, J AM CHEM SOC, V88, P5168

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