PRODUCTION OF FULLERENES BY LOW-TEMPERATURE PLASMA CHEMICAL-VAPOR-DEPOSITION UNDER ATMOSPHERIC-PRESSURE

被引：28

作者：

INOMATA, K ^{[1
]}

AOKI, N ^{[1
]}

KOINUMA, H ^{[1
]}

机构：

[1] TOKAI UNIV,FAC ENGN,HIRATSUKA,KANAGAWA 25912,JAPAN

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 1994年 / 33卷 / 2A期

关键词：

PRODUCTION OF FULLERENES; LOW TEMPERATURE; PLASMA CVD; ATMOSPHERIC PRESSURE; ORGANO COMPOUNDS AS SOURCE MATERIAL;

D O I：

10.1143/JJAP.33.L197

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A gas phase reactor developed for generating homogenous low temperature plasma under atmospheric pressure was found to provide a new method for producing fullerenes by a plasma chemical vapor deposition (CVD) process. Into an afterglow region of atmospheric pressure Ar-He mixed gas plasma, an aromatic hydrocarbon was introduced and decomposed into black soot under appropriate reaction conditions. A benzene solution of the soot showed two clear HPLC peaks with retention times corresponding well to those of C-60 and C-70. The formation of C-60 was further confirmed by UV spectroscopy.

引用

页码：L197 / L199

页数：3

共 7 条

[1] POLYHEDRAL CARBON-IONS IN HYDROCARBON FLAMES [J].

GERHARDT, P ;

LOFFLER, S ;

HOMANN, KH .

CHEMICAL PHYSICS LETTERS, 1987, 137 (04) :306-310

[2] EFFICIENT PRODUCTION OF C60 (BUCKMINSTERFULLERENE), C60H36, AND THE SOLVATED BUCKIDE ION [J].

HAUFLER, RE ;

CONCEICAO, J ;

CHIBANTE, LPF ;

CHAI, Y ;

BYRNE, NE ;

FLANAGAN, S ;

HALEY, MM ;

OBRIEN, SC ;

PAN, C ;

XIAO, Z ;

BILLUPS, WE ;

CIUFOLINI, MA ;

HAUGE, RH ;

MARGRAVE, JL ;

WILSON, LJ ;

CURL, RF ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8634-8636

[3] FULLERENES C60 AND C70 IN FLAMES [J].

HOWARD, JB ;

MCKINNON, JT ;

MAKAROVSKY, Y ;

LAFLEUR, AL ;

JOHNSON, ME .

NATURE, 1991, 352 (6331) :139-141

[4]

KOINUMA H, 1992, APPL PHYS LETT, V60, P86

[5] THE FORMATION OF QUASI-ICOSAHEDRAL SPIRAL SHELL CARBON PARTICLES [J].

KROTO, HW ;

MCKAY, K .

NATURE, 1988, 331 (6154) :328-331

[6] C-60 - BUCKMINSTERFULLERENE [J].

KROTO, HW ;

HEATH, JR ;

OBRIEN, SC ;

CURL, RF ;

SMALLEY, RE .

NATURE, 1985, 318 (6042) :162-163

[7]

YOSHIE K, 1992, APPL PHYS LETT, V61, P2773

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