DETERMINATION OF THE ELECTRIC-FIELD GRADIENTS FOR THE 2 DIFFERENT NUCLEAR SITES OF THE CADMIUM ATOMS IN BIS(THIOSEMICARBAZIDE) CADMIUM(II) SULFATE USING GAMMA-RAY PERTURBED ANGULAR-CORRELATION SPECTROSCOPY ON THE CD-111 ISOTOPE

被引：15

作者：

BAUER, R ^{[1
]}

CHRISTENSEN, C ^{[1
]}

LARSEN, E ^{[1
]}

机构：

[1] HC ORSTED INST,DEPT CHEM 1,DK-2100 COPENHAGEN,DENMARK

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 09期

关键词：

D O I：

10.1063/1.438036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gamma ray perturbed angular correlation spectra of IIICd 2+ in bis(thiosemicarbazide)cadmium(II) sulfate and in bis(thiosemicarbazide)zinc(II) sulfate have been recorded. From the measurements of IIICd in the cadmium complex of known structure two different sets of electric field gradient parameters have been evaluated. These observed quantities have been interpreted in a general ligand field model suitable to translate information about electric field gradients of metal ions of nd 10 electronic configruation into chemical bonding properties. © 1979 American Institute of Physics.

引用

页码：4117 / 4122

页数：6

共 26 条

[1]

ABLOV AV, 1971, RUSS J INORG CHEM, V16, P96

[2]

Bancroft G. M., 1972, ADV INORG CHEM, V15, P59

[3] METAL SITE STRUCTURE IN A PROTEIN STUDIED BY DIFFERENTIAL PERTURBED ANGULAR-CORRELATIONS [J].