On the electronic spectra of the duryl radical and the origin of the green emission of durene

被引：25

作者：

Leach, S. ^{[1
]}

Migirdicyan, Eva ^{[1
]}

机构：

[1] Fac Sci, Chim Phys Lab, Orsay 91, France

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80005-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The visible fluorescene, ultraviolet absorption and excitation spectra of the duryl (2, 4, 5-methyl-benzyl) radical at 77 degrees K have been observed after formation of the radical by photolysis of crystalline durene or rigid solutions. The transitions observed are analogues to those of the benzyl radical. The green emission of irradiated durene observed by Kallmann is attributed to the duryl first doublet-doublet flourescence.

引用

页码：21 / 22

页数：2

共 11 条

[1]

BERNARROCHE M, 1962, CR HEBD ACAD SCI, V254, P459

[2]

GOLDSTEIN E, 1911, VERH DEUTSCH PHYSIK, V13, P378

[3]

GRAJCAR L, 1964, J CHIM PHYS, V61, P1523

[4]

KAILMANN H, 1962, LUMINESCENCE ORGANIC, P244

[5]

LEACH S, 1962, LUMINESCENCE ORGANIC, P176

[6]

LEACH S, 1967, COMPT REND

[7]

MARTINBOUYER M, 1966, INT C LUMINESCENCE B, P139

[8] LUMINESCENCES PROPRES ET PARASITES DU DURENE [J].

MEYER, Y ;

ASTIER, R .

JOURNAL DE PHYSIQUE, 1963, 24 (12) :1089-1094

[9] POLARIZATION OF GREEN EMISSION FROM A DURENE CRYSTAL [J].

NAKAMURA, T ;

HAYAKAWA, S .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1963, 18 (06) :793-&

[10]

PORTER G, 1965, SPECTROCHIM ACTA, V22, P803

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