PREPARATION OF 2-SUBSTITUTED ARSABENZENES

被引：37

作者：

ASHE, AJ

CHAN, WT

机构：

[1] Department, of Chemistry, University of Michigan, Ann Arbor

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 09期

关键词：

D O I：

10.1021/jo01323a010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of 1, 4-diynes react with dibutyltin hydride to give predominately 2-alkyl-1, 1-dibutyl-l, 4-dihydrostannabenzenes. These may be readily converted to 2-alkylarsabenzenes by treatment with arsenic trichloride. In this manner, 6-acetoxy-1, 4-hexadiyne has been converted to 2-arsabenzyl acetate and hence to a number of 2-functionalized arsabenzenes. © 1979, American Chemical Society. All rights reserved.

引用

页码：1409 / 1413

页数：5

共 34 条

[1] 1-PHENYLBORABENZENE ANION
ASHE, AJ
SHU, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) : 1804 - &
[2] ASHE AJ, 1975, TETRAHEDRON LETT, P1083
[3] GROUP-5 HETEROBENZENES
ASHE, AJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (04) : 153 - 157
[4] ASHE AJ, 1978, TETRAHEDRON LETT, P2537
[5] ASHE AJ, 1975, TETRAHEDRON LETT, P2749
[6] NUCLEAR MAGNETIC-RESONANCE SPECTRA OF PHOSPHABENZENE, ARSABENZENE, AND STIBABENZENE
ASHE, AJ
SHARP, RR
TOLAN, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) : 5451 - 5456
[7] PHOSPHABENZENE AND ARSABENZENE
ASHE, AJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (13) : 3293 - &
[8] APPLICATIONS OF PHOTOELECTRON SPECTROSCOPY .41. PHOTOELECTRON SPECTRA OF PHOSPHABENZENE, ARSABENZENE, AND STIBABENZENE
BATICH, C
HEILBRON.E
HORNUNG, V
ASHE, AJ
CLARK, DT
COBLEY, UT
KILCAST, D
SCANLAN, I
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) : 928 - 930
[9] BRANDSMA L, 1971, PREPARATIVE ACETYLEN, P52
[10] CHAN WT, 1977, THESIS U MICHIGAN

← 1 2 3 4 →