OLIGO(9,10-ANTHRYLENES), ORGANIC-COMPOUNDS WITH STABLE HIGH-SPIN STATES

被引：62

作者：

BAUMGARTEN, M ^{[1
]}

MULLER, U ^{[1
]}

BOHNEN, A ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,ACKERMANNWEG 10,W-6500 MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 04期

关键词：

D O I：

10.1002/anie.199204481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

According to ESR spectroscopy and cyclic voltammetric experiments the soluble oligo(9,10-anthrylenes) 1 are unusual redox systems. Significant for the development of organic ferromagnets is the formation of high-spin states in such ion, which can carry one charge per anthracene unit. Even the heptamer 1 (R = n-hexyl, m = 2) was isolated in 18% yield.

引用

页码：448 / 451

页数：4

共 27 条

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