GAS-PHASE REACTIONS, .85. PREPARATION AND PHOTOELECTRON-SPECTRUM OF ETHYLDITHIOXO-LAMBDA-5-PHOSPHORANE H5C2-P(=S)2

被引：6

作者：

BOCK, H ^{[1
]}

KREMER, M ^{[1
]}

SOLOUKI, B ^{[1
]}

BINNEWIES, M ^{[1
]}

机构：

[1] UNIV FREIBURG,ANORGAN CHEM LAB,W-7800 FREIBURG,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 02期

关键词：

LAMBDA-5-PHOSPHORANES; PHOTOELECTRON SPECTROSCOPY;

D O I：

10.1002/cber.19921250207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first alkyldithioxo-lambda(5)-phosphorane 1a is obtained by selective monomerization of its readily accessible dimer, 2,4-diethyl-1,3,2-lambda(5),4-lambda(5)-dithiadiphosphetane-2,4-dithione [4 (R = C2H5)], at 970K in the gas phase and characterized by its photoelectron spectrum, which is assigned by both Koopmans' correlation and radical-cation state comparison with the halogen derivatives FPS2 (1b) and ClPS2 (1c).

引用

页码：315 / 320

页数：6

共 32 条

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