A FACILE, NOVEL WAY TO PREPARE ANIONIC, NEUTRAL AND CATIONIC GOLD(I) COMPLEXES

被引：60

作者：

VICENTE, J

CHICOTE, MT

SAURALLAMAS, I

LAGUNAS, MC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 12期

关键词：

D O I：

10.1039/c39920000915

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex ppn[Au(acac)2] 1 can be obtained by reacting ppn[AuCl2] with [Tl(acac)] in 1:2 molar ratio, dagger and complex 1 reacts with compounds of the type RH in which H has some acidic character to give the corresponding [AuR2]- species; RH = CH2(CN)2 2, CH2(CO2Me)2 3, CH2(CN)CO2Me 4, Me3SiCCH 5, 2-SH-C5H4N 6, AuR RH = CH2(PPh2)2, 7, or [AuR2]+ RH = [(4-MeC6H4)3PCH2C5H4N-2]ClO4 8.

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页码：915 / 916

页数：2

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