CHIRAL OXAZOLINYLFERROCENE-PHOSPHINE HYBRID LIGAND FOR THE ASYMMETRIC HYDROSILYLATION OF KETONES

被引：172

作者：

NISHIBAYASHI, Y ^{[1
]}

SEGAWA, K ^{[1
]}

OHE, K ^{[1
]}

UEMURA, S ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,KYOTO 60601,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1021/om00012a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A neu, type of chiral oxazolinylferrocene-phosphine hybrid is a very effective ligand for Rh(I)-catalyzed asymmetric hydrosilylation of simple ketones to give the corresponding sec-alcohols (91% ee) after acid hydrolysis. Similar reactions also proceed highly selectively (96% ee) by use of Ir(I) catalyst, but the configuration of the products is completely reverse.

引用

页码：5486 / 5487

页数：2

共 19 条

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