MULTIPLE METAL-CARBON BONDS .42. FORMATION OF TUNGSTENACYCLOBUTADIENE COMPLEXES CONTAINING A PROTON IN THE RING AND THEIR CONVERSION TO DEPROTIO TUNGSTENACYCLOBUTADIENE COMPLEXES

被引：45

作者：

FREUDENBERGER, JH ^{[1
]}

SCHROCK, RR ^{[1
]}

机构：

[1] MIT,DEPT CHEM,6-331,CAMBRIDGE,MA 02139

来源：

ORGANOMETALLICS | 1986年 / 5卷 / 07期

关键词：

D O I：

10.1021/om00138a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1411 / 1417

页数：7

共 12 条

[1] METATHESIS OF ACETYLENES BY TRIPHENOXYTUNGSTENACYCLOBUTADIENE COMPLEXES AND THE CRYSTAL-STRUCTURE OF W(C3ET3)[O-2,6-C6H3(I-PR)2]3 [J].

CHURCHILL, MR ;

ZILLER, JW ;

FREUDENBERGER, JH ;

SCHROCK, RR .

ORGANOMETALLICS, 1984, 3 (10) :1554-1562

[2] X-RAY STRUCTURAL-ANALYSIS OF W[C(T-BU)CHC(T-BU)][OCH(CF3)2]3, A MOLECULE CONTAINING A PLANAR TUNGSTENACYCLOBUTADIENE RING WITH NO ALKYL SUBSTITUENT ON THE BETA-CARBON ATOM [J].

CHURCHILL, MR ;

ZILLER, JW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 286 (01) :27-36

[3] MULTIPLE METAL-CARBON BONDS .37. PREPARATION OF DI-TERT-BUTOXYTUNGSTEN(VI) ALKYLIDENE COMPLEXES BY PROTONATION OF TRI-TERT-BUTOXYTUNGSTEN(VI) ALKYLIDENE COMPLEXES [J].

FREUDENBERGER, JH ;

SCHROCK, RR .

ORGANOMETALLICS, 1985, 4 (11) :1937-1944

[4] METATHESIS OF ACETYLENES BY (FLUOROALKOXY)TUNGSTENACYCLOBUTADIENE COMPLEXES AND THE CRYSTAL-STRUCTURE OF W(C3ET3)[OCH(CF3)2]3 - A HIGHER-ORDER MECHANISM FOR ACETYLENE METATHESIS [J].

FREUDENBERGER, JH ;

SCHROCK, RR ;

CHURCHILL, MR ;

RHEINGOLD, AL ;

ZILLER, JW .

ORGANOMETALLICS, 1984, 3 (10) :1563-1573

[5] MULTIPLE METAL-CARBON BONDS .35. A GENERAL-ROUTE TO TRI-TERT-BUTOXYTUNGSTEN ALKYLIDYNE COMPLEXES - SCISSION OF ACETYLENES BY DITUNGSTEN HEXA-TERT-BUTOXIDE [J].

LISTEMANN, ML ;

SCHROCK, RR .

ORGANOMETALLICS, 1985, 4 (01) :74-83

[6] MULTIPLE METAL-CARBON BONDS .38. PREPARATION OF TRIALKOXYMOLYBDENUM(VI) ALKYLIDYNE COMPLEXES, THEIR REACTIONS WITH ACETYLENES, AND THE X-RAY STRUCTURE OF MO[C3(CME3)2][OCH(CF3)2]2(C5H5N)2 [J].

MCCULLOUGH, LG ;

SCHROCK, RR ;

DEWAN, JC ;

MURDZEK, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) :5987-5998

[7] MULTIPLE METAL-CARBON BONDS .34. METATHESIS OF ACETYLENES BY MOLYBDENUM(VI) ALKYLIDYNE COMPLEXES [J].

MCCULLOUGH, LG ;

SCHROCK, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (14) :4067-4068

[8] MULTIPLE METAL-CARBON BONDS .34. WHY TERMINAL ALKYNES CANNOT BE METATHESIZED - PREPARATION AND CRYSTAL-STRUCTURE OF A DEPROTONATED TUNGSTENACYCLOBUTADIENE COMPLEX, W(ETA-5-C5H5)[C3(CME3)2]CL [J].

MCCULLOUGH, LG ;

LISTEMANN, ML ;

SCHROCK, RR ;

CHURCHILL, MR ;

ZILLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) :6729-6730

[9] MULTIPLE METAL-CARBON BONDS .39. PREPARATION OF MOLYBDENUM AND TUNGSTEN NEOPENTYLIDYNE COMPLEXES OF THE TYPE M(CCME3)(O2CR)3, THEIR REACTIONS WITH ACETYLENES, AND THE X-RAY STRUCTURE OF THE ETA-3-CYCLOPROPENYL COMPLEX W[C3(CME3)ET2](O2CCH3)3 [J].

SCHROCK, RR ;

MURDZEK, JS ;

FREUDENBERGER, JH ;

CHURCHILL, MR ;

ZILLER, JW .

ORGANOMETALLICS, 1986, 5 (01) :25-33

[10] RECENT ADVANCES IN THE CHEMISTRY OF WELL-DEFINED OLEFIN AND ACETYLENE METATHESIS CATALYSTS [J].

SCHROCK, RR ;

FREUDENBERGER, JH ;

LISTEMANN, ML ;

MCCULLOUGH, LG .

JOURNAL OF MOLECULAR CATALYSIS, 1985, 28 (1-3) :1-8

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