HETEROGENEOUS CHEMICAL OSCILLATOR - BELOUSOV-ZHABOTINSKII-TYPE REACTION OF OXALIC-ACID

被引：137

作者：

NOSZTICZIUS, Z

BODISS, J

机构：

[1] Institute of Physic, Technical University of Budapest

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 12期

关键词：

D O I：

10.1021/ja00506a007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of oscillating reaction, the heterogeneous Belousov-Zhabotinskii reaction of oxalic acid, is described. Periodic CO2 and Br2 evolution was measured with the aid of flame ionization and coulometric detectors. The stoichiometry of the reaction was determined and a radical mechanism was proposed based on experiments with acrylamide as a radical scavenger. A possible connection with the mechanism of the original Belousov reaction is mentioned. © 1979, American Chemical Society. All rights reserved.

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页码：3177 / 3182

页数：6

相关论文

共 20 条

[1] OXIDATION OF CEROUS IONS BY BROMATE IONS - COMPARISON OF EXPERIMENTAL-DATA WITH COMPUTER CALCULATIONS [J].

BARKIN, S ;

BIXON, M ;

NOYES, RM ;

BARELI, K .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1977, 9 (05) :841-862

[2]

BECK M, 1975, MAGY KEM FOLY, V81, P519

[3] OSCILLATING CHEMICAL-REACTIONS (BELOUSOV-ZHABOTINSKII TYPE) INVOLVING CYCLIC AND ALIPHATIC-KETONES [J].

FARAGE, VJ ;

STROOT, P ;

JANJIC, D .

HELVETICA CHIMICA ACTA, 1977, 60 (01) :231-236

[4]

FIELD RJ, 1974, J CHEM PHYS, V60, P1877, DOI 10.1063/1.1681288

[5] OSCILLATIONS IN CHEMICAL SYSTEMS .2. THOROUGH ANALYSIS OF TEMPORAL OSCILLATION IN BROMATE-CERIUM-MALONIC ACID SYSTEM [J].

FIELD, RJ ;

NOYES, RM ;

KOROS, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (25) :8649-&

[6]

FRANCK U, 1970, NATURWISSENSCHAFTEN, V58, P52

[7] BELOUSOV OSCILLATION REACTION .1. BROMATE-CERIUM REACTION-KINETICS [J].

HERBO, C ;

SCHMITZ, G ;

VANGLABBEKE, M .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (16) :2628-2638

[8] OSCILLATIONS IN CHEMICAL SYSTEMS .9. REACTIONS OF CERIUM(IV) WITH MALONIC-ACID AND ITS DERIVATIVES [J].

JWO, JJ ;

NOYES, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (19) :5422-5431

[9]

KASPEREK GJ, 1971, INORG CHEM, V10, P382

[10] THE OXIDATION OF OXALIC ACID AND OXALATE BY BROMINE AND THE ROLE OF THE POSITIVE BROMINE ION [J].

KNOLLER, Y ;

PERLMUTTERHAYMAN, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (12) :3212-3214