STIMULATED-EMISSION PUMPING OF VANDERWAALS VIBRATIONS IN THE GROUND ELECTRONIC STATE OF OH-AR

被引：77

作者：

BERRY, MT ^{[1
]}

BRUSTEIN, MR ^{[1
]}

LESTER, MI ^{[1
]}

CHAKRAVARTY, C ^{[1
]}

CLARY, DC ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, DEPT CHEM, CAMBRIDGE CB2 1EW, ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 178卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(91)87073-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Stimulated emission spectroscopy is used to measure the frequencies of the van der Waals bending and stretching modes in the ground electronic state of the OH-Ar complex correlating with OH(X 2-PI) + Ar(S-1(0)). The results are compared with those predicted using an ab initio potential energy surface. Encouraging agreement between experiment and theory is obtained, particularly for the van der Waals bending modes.

引用

页码：301 / 310

页数：10

共 23 条

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