LACTONE ANNULATION OF BETA-KETO-ESTERS WITH BETA-VINYLBUTENOLIDE AND THE TOTAL SYNTHESIS OF RACEMIC FRULLANOLIDE

被引：58

作者：

KIDO, F ^{[1
]}

TSUTSUMI, K ^{[1
]}

MARUTA, R ^{[1
]}

YOSHIKOSHI, A ^{[1
]}

机构：

[1] TOHOKU UNIV,CHEM RES INST NON AQUEOUS SOLUT,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 21期

关键词：

D O I：

10.1021/ja00515a043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new annulation reaction, in which sodium enolates of β-keto esters 6-11 and β-vinylbutenolide (2) yield lactone annulated products 12-17 in one step, is described. Racemic frullanolide (30) has been synthesized from one of these annulation products, 14a. © 1979, American Chemical Society. All rights reserved.

引用

页码：6420 / 6424

页数：5

共 19 条

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