PULSED-NOZZLE FOURIER-TRANSFORM MICROWAVE SPECTROSCOPY OF THE BENZENE-N-15(2) COMPLEX

被引：45

作者：

OHSHIMA, Y

KOHGUCHI, H

ENDO, Y

机构：

[1] Department of Pure and Applied Sciences, The College of Arts and Sciences, The University of Tokyo, Meguro-ku, Tokyo, 153, Komaba

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 184卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(91)87158-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The pure rotational spectrum of the benzene-N-15(2) complex has been observed by a pulsed-nozzle Fourier-transform microwave spectrometer. The observed spectrum consists of two internal-rotation states and evidently shows the existence of an almost-free rotational motion of N2 within the complex. The rotational and centrifugal-distortion constants for the ground internal-rotation state have been determined precisely. An analysis of the centrifugal-distortion constants has been carried out to derive information on the intermolecular vibrations.

引用

页码：21 / 24

页数：4

共 17 条

[1] FABRY-PEROT CAVITY PULSED FOURIER-TRANSFORM MICROWAVE SPECTROMETER WITH A PULSED NOZZLE PARTICLE SOURCE [J].

BALLE, TJ ;

FLYGARE, WH .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1981, 52 (01) :33-45

[2]

BALOCCHI FA, 1983, J PHYS CHEM-US, V87, P2079, DOI 10.1021/j100235a012

[3] ROTATIONAL ANALYSIS OF THE 1B2U(PI-PI-STAR) ]-1A1G(610) BAND OF BENZENE AND HELIUM-BENZENE VANDERWAALS COMPLEXES IN A SUPERSONIC JET [J].

BECK, SM ;

LIVERMAN, MG ;

MONTS, DL ;

SMALLEY, RE .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) :232-237

[4] ROTATIONAL SPECTRUM AND DIPOLE-MOMENT OF THE BENZENE-ARGON VANDERWAALS COMPLEX [J].

BRUPBACHER, T ;

BAUDER, A .

CHEMICAL PHYSICS LETTERS, 1990, 173 (5-6) :435-438

[5] STRUCTURE OF THE BENZENE-ARGON COMPLEX IN THE GAS-PHASE AT 3 KELVIN [J].

FUNG, KH ;

SELZLE, HL ;

SCHLAG, EW .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1981, 36 (12) :1338-1339

[6]

Gordy W., 1970, MICROWAVE MOL SPECTR

[7]

Huber K. P., 1979, CONSTANTS DIATOMIC M, DOI DOI 10.1007/978-1-4757-0961-2_2

[8] ROTATIONAL SPECTRA, STRUCTURE, AND INTRAMOLECULAR FORCE-FIELD OF THE HG-OCS VANDERWAALS COMPLEX [J].

IIDA, M ;

OHSHIMA, Y ;

ENDO, Y .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (11) :6989-6994

[9] CALCULATION OF THE VIBRONIC STRUCTURE OF SOLUTE SOLVENT VANDERWAALS CLUSTERS [J].

MENAPACE, JA ;

BERNSTEIN, ER .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (10) :2533-2544

[10] BENZENE CLUSTERED WITH N2, CO2, AND CO - ENERGY-LEVELS, VIBRATIONAL STRUCTURE, AND NUCLEATION [J].

NOWAK, R ;

MENAPACE, JA ;

BERNSTEIN, ER .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (03) :1309-1321

← 1 2 →