SYNTHESIS AND X-RAY-DIFFRACTION CRYSTAL-STRUCTURE OF ZN(N[(C(CH3)3)(SI(CH3)3)])2. THE 1ST SOLID-STATE CHARACTERIZATION OF A HOMOLEPTIC ZINC AMIDE

被引:34
作者
REES, WS [1 ]
GREEN, DM [1 ]
HESSE, W [1 ]
机构
[1] FLORIDA STATE UNIV,CTR MAT RES & TECHNOL,TALLAHASSEE,FL 32306
关键词
D O I
10.1016/S0277-5387(00)83726-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction between ZnCl2 and two equivalents of {Li}{N[(C(CH3)3) (Si(CH3)3)]} in THF at ambient temperature yields the distillable white solid Zn{N[(C(CH3)3)(Si(CH3)3)]}2, which is the first homoleptic zinc amide to be structurally characterized in the solid state.
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页码:1697 / 1699
页数:3
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