X-RAY-DIFFRACTION AND F-19 AND TL-205 NMR EVIDENCE FOR ELECTROPHILE BINDING TO AN ORGANOFLUORINE SUBSTITUENT

被引：20

作者：

SAMUELS, JA

ZWANZIGER, JW

LOBKOVSKY, EB

CAULTON, KG

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[2] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 20期

关键词：

D O I：

10.1021/ic00046a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solid-state structural and variable-temperature multinuclear NMR evidence supports the idea that thallium is held within the molecular compound Tl2-Zr[OCH(CF3)2]6 in part by fluorine/thallium interactions. Thallium migrates rapidly over the entire surface of the Zr[OCH(CF3)2]62- octahedron, however.

引用

页码：4046 / 4047

页数：2

共 12 条

[1]

ABUBAKAR WAW, 1989, J CHEM SOC DA, P991

[2]

ALCOCK NW, 1969, ACTA CRYSTALLOGR A, V25, P5101

[3] TRANSITION-METAL FLUORO COMPOUNDS CONTAINING CARBONYL, PHOSPHINE, ARSINE, AND STIBINE LIGANDS [J].