SYNTHESIS OF TETRAALKYLTHIO-SUBSTITUTED PHTHALOCYANINES AND THEIR COMPLEXATION WITH AG(I) AND PD(II)

被引：99

作者：

GUROL, I

AHSEN, V

BEKAROGLU, O

机构：

[1] TUBITAK,MARMARA RES CTR,DEPT CHEM,POB 21,41470 GEBZE,TURKEY

[2] TECH UNIV ISTANBUL,DEPT CHEM,ISTANBUL,TURKEY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 04期

关键词：

D O I：

10.1039/dt9940000497

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of new metal-free and nickel(II) phthalocyanines substituted with four alkylthio groups SR (R = dodecyl or hexadecyl) is described. The new compounds have been characterized by elemental analyses, and IR, H-1 NMR and UV/VIS spectroscopy. The thio donors co-ordinate to Ag(I) and Pd(II) to give 2:1 metal-nickel phthalocyanine species. The changes in the electronic spectra with respect to increasing concentration of Pd(II) or Ag(I) have been investigated.

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页码：497 / 500

页数：4

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