CHIRAL DISCRIMINATION IN THE LIQUID-PHASE - EXCESS VOLUMES OF BINARY-MIXTURES OF AMINO-ACID DERIVATIVES

被引:16
作者
LEPORI, L [1 ]
KOPPENHOEFER, B [1 ]
机构
[1] UNIV TUBINGEN,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY
关键词
D O I
10.1021/j100078a031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Volume changes on mixing the enantiomers of N-trifluoroacetylamino acid methyl esters (N-TFA-amino acid-OMe) were determined at 25 degrees C by means of a high-precision vibrating-tube densimeter. The excess molar volumes (V-E) for the racemic mixtures of N-TFA-Ala-OMe 1, N-TFA-Val-OMe 2, and N-TFA-Leu-OMe 3, were found as V-E = 0.0098, -0.0458, and 0.035 cm(3) mol(-1), respectively. For 2 and 3, these volumetric effects of discriminating interactions between enantiomers in the liquid phase are the largest ever observed.
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页码:6862 / 6864
页数:3
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