MATHEMATICAL-MODELING OF A NICKEL-CADMIUM BATTERY - EFFECTS OF INTERCALATION AND OXYGEN REACTIONS

被引:42
作者
FAN, DY
WHITE, RE
机构
[1] Center for Electrochemical Engineering, Department of Chemical Engineering, Texas A&M University, Texas 77843, College Station
关键词
D O I
10.1149/1.2085347
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Extensions are presented for a previously published (1) mathematical model of a nickel-cadmium (Ni-Cd) cell. These extensions consist of intercalation thermodynamics for the nickel electrode and oxygen generation and reduction reactions during charge and overcharge. The simulated results indicate that intercalation may be important in the nickel electrode and that including the oxygen reactions provides a means of predicting the efficiency of the cell on charge and discharge.
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页码:2952 / 2960
页数:9
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